第1回・大学で勉強する化学ってどんなの?〜分子の結合について〜

こんにちは!

ゴールデンウィークも終わり、また元の生活に戻りましたね。

さて、たまには大学で習う化学に足を踏み入れてみましょう。

今日は「分子の結合」についてお話します。高校生でも習いませんし、大学の教育学部でも習わないので、学校の先生も知らないかもしれません。

水素分子を例にして考えてみましょう!!
水素分子は水素原子が2個くっついたものです。

水素原子では、1個の陽子(原子核)の周りを1個の電子がまわっています。
水素分子では、2個の陽子(原子核)の周りを2個の電子がまわっています。

さて、質問です。
どうして水素分子はバラバラになって水素原子2個にならないのでしょうか?

答えは、電子が2個の原子核を引きつけているからです。

水素分子が水素原子Aと水素原子Bの2個で成り立っているとしましょう。そうすると、電子が水素原子AとBの両方を引き付けるため、水素の原子核が離れて分子が原子に分かれるということは起きません。

これを分子の「結合」といいます。結合に関与している電子は水素原子A,Bの間にいる確率が高いのですが、ビュンビュン動いているので電子2個とも原子核から離れているようなときもあります。電子のいる場所によって原子核の引き寄せられ方が変わるので、原子Aと原子Bの距離が変わります。これを分子の「振動」といいます。

分子によって分子の振動数が違うので、これを測定することで分子を見分けることができます。一種の科学捜査ですね笑。

そしてさらにTHE・理系の大学生しか習わないことですが、、、
上記のように2個の電子があれば分子結合を形成することができます。しかし、子は2種類あります!!実は、結合を形成できるのは違う種類の電子同士の組み合わせのときだけなのです。

電子は、磁石の影響をうけます。そして、N極に近づく電子とS極に近づく電子の2種類があります。つまり、電子自身が小さな磁石としての性質をもっているのです。したがって、同じ種類の電子は反発し合い、分子の結合を形成することができません。なので、分子結合は必ず2種類の電子によって形成されています。

分子は複数の原子がつながって出来たものですが、原子にもちょうど良い距離というものがあります。これを「平衡核間距離」といいます。原子同士はあまり近づき過ぎると、+の電気をもつ原子核同士が反発するためお互いを退け合います。逆に、あまり遠ざかりすぎると、電子が放っといてくれないのでまた近づきます。

分子の結合の様子をみていると、人間関係に似ているような気がします。あまり近づき過ぎると居心地悪いけど、全く喋らないのも寂しい…そんな人居ますよね笑。クラスの友達とうまく行かない時は、「むっ、ここは平衡核間距離ではない!」と思ってうまく距離感を調整してみてください笑。

今後はこのように大学で勉強する化学のことなども紹介していけたらなと思っております。何かリクエストがあれば、Twitterアカウントの方へお願いします!

それでは。

118 thoughts on “第1回・大学で勉強する化学ってどんなの?〜分子の結合について〜”

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