電気分解と電池

電子が動くことで電流がうまれます。まずはイオンが動く様子をみてみましょう。

電気分解
電気を通す棒に電流を流すと、電池の+極側が陽極-極側が陰極になります。

 <ポイント1>
陽イオン→陰極へ
陰イオン→陽極へ

静電気の力でイオンが電極に引きつけられるわけですね。
上図では塩化銅(CuCl2)がCuとCl2にわかれる様子を描きました。

<ポイント2>
電流の向きと電子の向きは逆向き

<ポイント3>
電気分解が進むと、水溶液の色がうすくなる
実はCu2+青色のイオンなのです。
電気分解が進んで水溶液内のCu2+が減ると、水溶液は青色から無色へと変化します。

電池
電池では「2種類の金属板を組み合わせる」ことが大切です。
 ー極となる金属が電子を放出して陽イオンになります。このときに放出される電子が導線を移動して電流が流れます。

<ポイント>
ー極→電子を放出し、イオンになる
+極→近くで陽イオンの気体が発生

イオン化傾向は高校で習うものなので参考程度に紹介しました。
イオンになるのはー極なので、イオン化傾向が高いとー極になります。
どちらかがイオンになる必要があるので、同じ金属板を2枚つかっても電池にはなりません

電池の原理を忘れそうな人は、Znが電子を2つ放出してZn2+になるのがスタートであることを意識して覚えましょう!


<コメント>
電気分解では「陽極」と「陰極」ですが、電池では「+極」と「ー極」です。
<ポイント>の部分さえ抑えれば、簡単に問題を解けると思います。
Cu2+が青色であることを紹介しましたが、他にも発色するイオンはたくさんあります。
Cu2+もまわりにいる分子の種類によって色が変わったりします!興味がある人は調べてみましょう!

(おわり)

113 thoughts on “電気分解と電池”

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